Probing nonlocal correlations in magnetic rare-earth clusters

Understanding and quantifying entanglement entropy is crucial to characterize the quantum behaviors that drive phenomena in a variety of systems. Rare-earth spin complexes, with their unique magnetic properties, provide fertile ground for exploring these nonlocal correlations. In this work, we study ${\mathrm{Eu}}^{2+}$ ions deposited on a Au(111) substrate, modeling finite clusters of large spin moments using a Heisenberg Hamiltonian parametrized by first-principles calculations. Our analysis reveals a one-to-one correspondence between structures in the differential conductance profiles and changes in the von Neumann entanglement entropy of bipartite subsystems, influenced by probe-ion separation and applied magnetic fields. Distinct braiding patterns in the conductance profiles are shown to correspond to stepwise changes in the entanglement entropy, providing a new avenue for investigating quantum correlations. These results establish a foundation for experimentally probing and controlling entanglement in lanthanide-based systems, with potential applications in quantum technologies.