On 2-stage martensitic transformation behavior in aged Ti<sub>50.5</sub>Ni<sub>33.5</sub>Cu<sub>11.5</sub>Pd<sub>4.5</sub> alloys with near-zero thermal hysteresis

Abstract The microstructures and martensitic transformation of a Ti-rich Ti 50.5 Ni 33.5 Cu 11.5 Pd 4.5 alloy aged at 500 °C for durations ranging from 15 min to 25 h were systematically investigated. With increasing aging time, the precipitates exhibit continuous growth; however, their quantity initially increases and subsequently decreases. The morphology of the precipitates evolves from granular to lamellar forms. Post-aging treatment, the transformation sequence transitions from a one-stage (B2–B19) to a two-stage process (B2 1 –B19 1 and B2 2 –B19 2 ) due to the precipitation of Ti 2 Cu-type particles, maintaining near-zero hysteresis. The two-stage martensitic transformation originates from the combined effects of stress distribution heterogeneities and variations in Ni content induced by aging precipitation.

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Publication Details

Journal
International Journal of Materials Research (formerly Zeitschrift fuer Metallkunde)
Published
2025-02-01
DOI
https://doi.org/10.1515/ijmr-2024-0022
Primary Topic
Shape Memory Alloy Transformations
Type
article
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article

On 2-stage martensitic transformation behavior in aged Ti50.5Ni33.5Cu11.5Pd4.5 alloys with near-zero thermal hysteresis

Y. Cai, Xiangjiu Guan, Hang Li, Xianglong Meng et al.
International Journal of Materials Research (formerly Zeitschrift fuer Metallkunde)
Shape Memory Alloy Transformations
article

On 2-stage martensitic transformation behavior in aged Ti50.5Ni33.5Cu11.5Pd4.5 alloys with near-zero thermal hysteresis

Y. Cai, Xiangjiu Guan, Hang Li, Xianglong Meng, Wei Cai, Lili Chen
article en

Abstract

Abstract The microstructures and martensitic transformation of a Ti-rich Ti 50.5 Ni 33.5 Cu 11.5 Pd 4.5 alloy aged at 500 °C for durations ranging from 15 min to 25 h were systematically investigated. With increasing aging time, the precipitates exhibit continuous growth; however, their quantity initially increases and subsequently decreases. The morphology of the precipitates evolves from granular to lamellar forms. Post-aging treatment, the transformation sequence transitions from a one-stage (B2–B19) to a two-stage process (B2 1 –B19 1 and B2 2 –B19 2 ) due to the precipitation of Ti 2 Cu-type particles, maintaining near-zero hysteresis. The two-stage martensitic transformation originates from the combined effects of stress distribution heterogeneities and variations in Ni content induced by aging precipitation.

International Journal of Materials Research (formerly Zeitschrift fuer Metallkunde)Vol. 116(2)
Shihezi University (CN), Heilongjiang University of Science and Technology (CN), Harbin Institute of Technology (CN)
Clean water and sanitation
Openalex Percentile: Top 99%
Shape Memory Alloy Transformations
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