The Influence of Spin-Orbit Coupling on the Efficiency of Optical Transitions in NeAr+ Molecular Ion
Using the NeAr+ weakly-bound ion as an example, we discuss the dependences of oscillator strengths of electric and magnetic dipole transitions in the weakly-bound heteronuclear rare gas ions on the spin-orbit coupling. We show that even when the spin-orbit coupling magnitude is small, its role in the optical transitions in the weakly-bound systems is not limited to line splitting. The correlation between the typical magnitude of the spin-orbit coupling energy, the splitting of the unperturbed terms and the change in the oscillator strengths of the electric and magnetic dipole transitions is demonstrated.
Authors
- A. A. Narits (ORCID: https://orcid.org/0000-0002-2793-1812)
Institutions
- P.N. Lebedev Physical Institute of the Russian Academy of Sciences (RU)
Publication Details
- Journal
- Bulletin of the Lebedev Physics Institute
- Published
- 2024-12-01
- DOI
- https://doi.org/10.3103/s1068335624602152
- Primary Topic
- Lanthanide and Transition Metal Complexes
- Type
- article
- Field-Weighted Citation Impact
- 0.00