The Influence of Spin-Orbit Coupling on the Efficiency of Optical Transitions in NeAr+ Molecular Ion

Using the NeAr+ weakly-bound ion as an example, we discuss the dependences of oscillator strengths of electric and magnetic dipole transitions in the weakly-bound heteronuclear rare gas ions on the spin-orbit coupling. We show that even when the spin-orbit coupling magnitude is small, its role in the optical transitions in the weakly-bound systems is not limited to line splitting. The correlation between the typical magnitude of the spin-orbit coupling energy, the splitting of the unperturbed terms and the change in the oscillator strengths of the electric and magnetic dipole transitions is demonstrated.

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Publication Details

Journal
Bulletin of the Lebedev Physics Institute
Published
2024-12-01
DOI
https://doi.org/10.3103/s1068335624602152
Primary Topic
Lanthanide and Transition Metal Complexes
Type
article
Field-Weighted Citation Impact
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article

The Influence of Spin-Orbit Coupling on the Efficiency of Optical Transitions in NeAr+ Molecular Ion

A. A. Narits
Bulletin of the Lebedev Physics Institute
Lanthanide and Transition Metal Complexes
article

The Influence of Spin-Orbit Coupling on the Efficiency of Optical Transitions in NeAr+ Molecular Ion

A. A. Narits
article en

Abstract

Using the NeAr+ weakly-bound ion as an example, we discuss the dependences of oscillator strengths of electric and magnetic dipole transitions in the weakly-bound heteronuclear rare gas ions on the spin-orbit coupling. We show that even when the spin-orbit coupling magnitude is small, its role in the optical transitions in the weakly-bound systems is not limited to line splitting. The correlation between the typical magnitude of the spin-orbit coupling energy, the splitting of the unperturbed terms and the change in the oscillator strengths of the electric and magnetic dipole transitions is demonstrated.

Bulletin of the Lebedev Physics InstituteVol. 51(12)
P.N. Lebedev Physical Institute of the Russian Academy of Sciences (RU)
Affordable and clean energy
Openalex Percentile: Top 83%
Lanthanide and Transition Metal Complexes
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