Influence of the SrVO3 thin film thickness integrated on glass thanks to [Ca2Nb3O10]- nanosheets

• One Step Integration of SrVO 3 on glass with CNO nanosheets . • Evidence for a 2D growth mechanism of SVO on nanosheet seed layers. • Thickness effect on electron conductivity properties. • Thickness dependence of the local conductivity of SrVO 3 films determined by SSRM Scanning Probe Microscopy . Nanosheets (NS) provide an innovative method for growing perovskite thin films on diverse substrates like glass and silicon, serving as germination seeds and offering a cost-effective alternative to expensive monocrystalline substrates. According to the NS transfer process onto the substrate, more than 85–90 % of the substrate is covered. However, a small fraction of the perovskite film grows directly on the substrate. This raises several questions: Is the perovskite film grown on glass conductive? How does the NS network influence electrical properties at macroscopic and submicron scales? To address these questions, we investigated the impact of thickness on the transport properties of transparent conductive SrVO 3 vanadate deposited on glass coated with [Ca2Nb3O10]- nanosheets (CNO NS). Macroscopic measurements revealed significant degradation of transport properties at thicknesses below 15 nm. In-plane local electrical properties were examined using Scanning Spreading Resistance Microscopy. Our findings indicate that local transport remains nearly constant when SrVO 3 is grown on NS, while a strong thickness dependence is observed when SrVO 3 is directly deposited on glass. These results contribute to a better understanding of the growth process, the integration of functional oxides on NS and open new perspectives for tuning the properties of vanadate films as transparent electrodes.

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Publication Details

Journal
Applied Surface Science
Published
2025-02-01
DOI
https://doi.org/10.1016/j.apsusc.2025.162580
Primary Topic
ZnO doping and properties
Type
article
Field-Weighted Citation Impact
0.00

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article

Influence of the SrVO3 thin film thickness integrated on glass thanks to [Ca2Nb3O10]- nanosheets

Valérie Demange, Rosine Coq Germanicus, Ulrike Lüders, Sandrine Froissart et al.
3 links
Applied Surface Science
ZnO doping and properties
article

Influence of the SrVO3 thin film thickness integrated on glass thanks to [Ca2Nb3O10]- nanosheets

Valérie Demange, Rosine Coq Germanicus, Ulrike Lüders, Sandrine Froissart, A. Boileau, Adrian David, Mohammad Darzinezhad Rami, Marie Dallocchio, Yves Dumont, Maryline Guilloux‐Viry, Simon Hurand, Arnaud Fouchet, Florent Baudouin, W. Prellier, Antoine Ruyter, B. Bérini
article en

Abstract

• One Step Integration of SrVO 3 on glass with CNO nanosheets . • Evidence for a 2D growth mechanism of SVO on nanosheet seed layers. • Thickness effect on electron conductivity properties. • Thickness dependence of the local conductivity of SrVO 3 films determined by SSRM Scanning Probe Microscopy . Nanosheets (NS) provide an innovative method for growing perovskite thin films on diverse substrates like glass and silicon, serving as germination seeds and offering a cost-effective alternative to expensive monocrystalline substrates. According to the NS transfer process onto the substrate, more than 85–90 % of the substrate is covered. However, a small fraction of the perovskite film grows directly on the substrate. This raises several questions: Is the perovskite film grown on glass conductive? How does the NS network influence electrical properties at macroscopic and submicron scales? To address these questions, we investigated the impact of thickness on the transport properties of transparent conductive SrVO 3 vanadate deposited on glass coated with [Ca2Nb3O10]- nanosheets (CNO NS). Macroscopic measurements revealed significant degradation of transport properties at thicknesses below 15 nm. In-plane local electrical properties were examined using Scanning Spreading Resistance Microscopy. Our findings indicate that local transport remains nearly constant when SrVO 3 is grown on NS, while a strong thickness dependence is observed when SrVO 3 is directly deposited on glass. These results contribute to a better understanding of the growth process, the integration of functional oxides on NS and open new perspectives for tuning the properties of vanadate films as transparent electrodes.

Applied Surface ScienceVol. 690
Centre National de la Recherche Scientifique (FR), Université de Versailles Saint-Quentin-en-Yvelines (FR), Université Paris-Saclay (FR), Institut Pprime (FR), Université Rennes 2 (FR), Institut des Sciences Chimiques de Rennes (FR), Normandie Université (FR), Groupe d’Étude de la Matière Condensée (FR), Laboratoire de Cristallographie et Sciences des Matériaux (FR), Université de Rennes (FR), Université de Caen Normandie (FR)
Agence Nationale de la Recherche
Openalex Percentile: Top 99%
ZnO doping and properties
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