Preparation of Resin Particles with Core-Shell Structure Using a Planetary Ball Mill and Evaluation of Heat Resistance Property

In this study, core-shell type particles with a membrane-like shell layer were prepared using a planetary ball mill. Tg = 63°C particles (8.7 μm) and Tg = 32°C particles (7.4 μm) containing a low melting point material were used for the core particles, and water suspension of acrylic particles (150 nm) were used for the shell material. Cross-sectional observation showed a membrane-like shell layer with no visible interfaces was produced on the core surface. This is because the shell particles uniformly adhered to the core particle surface, followed by the close packing and deformation due to the capillary force and curing during the vacuum drying. When the processed particles were heated in an oven at the temperature of the Tg of processed particles, no thermal aggregation and seepage of the low melting point material were observed. It was found that the shell layer effectively protected the core particles.