Room temperature magnetocaloric effects in monoclinic Cr3Te4

We report a systematic investigation of anisotropic magnetocaloric effects in a crystalline, monoclinic Cr3Te4 sample grown by the chemical vapor transport (CVT) method. The maximum magnetic entropy change −ΔSmaxM is 3.31 J kg−1 K−1 for the c axis (3.16 J kg−1 K−1 for the ab-plane) and the relative cooling power (RCP) is 340 J kg−1 for the c axis (350 J kg−1 for the ab-plane) near the Curie temperature with a magnetic field (μ0H) change of 9 T. With the scaling analysis of ΔSM, all rescaled ΔSM(T, H) curves collapse onto a single universal curve, indicating a second-order magnetic phase transition in Cr3Te4. Furthermore, −ΔSmaxM follows the power law of Hn with n = 0.656 ± 0.005. The RCP and δTFWHM have Hc and Hb dependence on field, with c = 1.179 ± 0.011 and b = 0.498 ± 0.005, respectively, which led us to estimate the critical exponents of β = 0.359 ± 0.013, γ = 1.646 ± 0.057, and δ = 5.578 ± 0.190.

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Publication Details

Journal
Journal of Applied Physics
Published
2025-01-28
DOI
https://doi.org/10.1063/5.0234906
Primary Topic
Magnetic and transport properties of perovskites and related materials
Type
article
Field-Weighted Citation Impact
0.00

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article

Room temperature magnetocaloric effects in monoclinic Cr3Te4

Emmanuel Yakubu, Samaresh Guchhait, Nicholas Ng, Anirban Goswami
Journal of Applied Physics
Magnetic and transport properties of perovskites and related materials
article

Room temperature magnetocaloric effects in monoclinic Cr3Te4

Emmanuel Yakubu, Samaresh Guchhait, Nicholas Ng, Anirban Goswami
article en

Abstract

We report a systematic investigation of anisotropic magnetocaloric effects in a crystalline, monoclinic Cr3Te4 sample grown by the chemical vapor transport (CVT) method. The maximum magnetic entropy change −ΔSmaxM is 3.31 J kg−1 K−1 for the c axis (3.16 J kg−1 K−1 for the ab-plane) and the relative cooling power (RCP) is 340 J kg−1 for the c axis (350 J kg−1 for the ab-plane) near the Curie temperature with a magnetic field (μ0H) change of 9 T. With the scaling analysis of ΔSM, all rescaled ΔSM(T, H) curves collapse onto a single universal curve, indicating a second-order magnetic phase transition in Cr3Te4. Furthermore, −ΔSmaxM follows the power law of Hn with n = 0.656 ± 0.005. The RCP and δTFWHM have Hc and Hb dependence on field, with c = 1.179 ± 0.011 and b = 0.498 ± 0.005, respectively, which led us to estimate the critical exponents of β = 0.359 ± 0.013, γ = 1.646 ± 0.057, and δ = 5.578 ± 0.190.

Journal of Applied PhysicsVol. 137(4)
Howard University (US), Johns Hopkins University (US)
National Science Foundation, Division of Materials Research
Openalex Percentile: Top 99%
Magnetic and transport properties of perovskites and related materials
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