The SI unit mole and Avogadro constant

The SI (2019) states that amount of substance is proportional to the number of entities in a sample, and the reciprocal of the proportionality factor is called the Avogadro constant N A . The SI suggests that the same approach that is used to redefine the other base units (based on the defining constants Δ ν Cs , c , h , e , k , and K cd ) is also used to redefine the mole based on N A . We contend that (i) 1 mol of all samples contains a fixed number of entities, which the SI calls the Avogadro number, (ii) amount of substance is a value on the scale of measurement defined by the mole, and (iii) the 2019 SI Avogadro number (6.022 140 76 × 10 23 ) is the established value of the 1970 SI Avogadro number, which is a constant physical quantity. The Avogadro constant is not required to define the unit mole or amount of substance.

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Publication Details

Journal
Measurement Sensors
Published
2025-01-29
DOI
https://doi.org/10.1016/j.measen.2024.101767
Primary Topic
Scientific Measurement and Uncertainty Evaluation
Type
article
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article

The SI unit mole and Avogadro constant

Karl K. Irikura, Raghu N. Kacker
1 links
Measurement Sensors
Scientific Measurement and Uncertainty Evaluation
article

The SI unit mole and Avogadro constant

Karl K. Irikura, Raghu N. Kacker
article en

Abstract

The SI (2019) states that amount of substance is proportional to the number of entities in a sample, and the reciprocal of the proportionality factor is called the Avogadro constant N A . The SI suggests that the same approach that is used to redefine the other base units (based on the defining constants Δ ν Cs , c , h , e , k , and K cd ) is also used to redefine the mole based on N A . We contend that (i) 1 mol of all samples contains a fixed number of entities, which the SI calls the Avogadro number, (ii) amount of substance is a value on the scale of measurement defined by the mole, and (iii) the 2019 SI Avogadro number (6.022 140 76 × 10 23 ) is the established value of the 1970 SI Avogadro number, which is a constant physical quantity. The Avogadro constant is not required to define the unit mole or amount of substance.

Measurement SensorsVol. 38
National Institute of Standards and Technology (US)
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Openalex Percentile: Top 98%
Scientific Measurement and Uncertainty Evaluation
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The SI unit mole and Avogadro constant — Karl K. Irikura, Raghu N. Kacker · Measurement Sensors (2025) | TGRS Research Map | TGRS