Conversion of Non-biodegradable Super Absorbing Polymer (SAP) Waste into MnO-rich Functional Supercapacitor Carbon by a Sustainable, Low-Temperature Activation Process
A non-biodegradable super absorbing polymer (SAP) is primarily used in biomedical devices and female menstrual sanitary waste pads. Its safe disposal is a massive problem that needs global strategic cognizance. The sanitary waste is mainly comprised of high molecular weight acrylate-based polymers having higher water-absorbent properties with a significant carbon atom-based cross-linked backbone. Here we have derived a workable energy storage material from menstrual sanitary waste with minimal energy input, making it environmentally viable. In this study, a rich carbon matrix was produced from pyrolysis of sanitary waste pads with KMnO4 based activation at 300 °C. The obtained carbon showed the presence of MnO moieties having desirable properties as a supercapacitor electrode. The stored energy density in the synthesized carbons was found to be 11.23 Wh kg–1 at a 0.275 kW kg–1 power density. The derived carbon shows excellent capacity retention of 84% and electrochemical stability until 10,000 cycles. These porous functional carbons produced from non-biodegradable SAPs thus make a sustainable potential resource for energy storage applications.
Authors
- Suresh Gosavi (ORCID: https://orcid.org/0000-0001-7540-0664)
- Aparna Deshpande
- Kiran Manohar
- Shivam Rawat (ORCID: https://orcid.org/0009-0000-9635-9103)
- Sadhana Rayalu
- Sarika Jadhav
Institutions
- Tokyo University of Science (JP)
- The University of Melbourne (AU)
- National Environmental Engineering Research Institute (IN)
- Indian Institute of Science Education and Research Pune (IN)
- Indian Institute of Petroleum (IN)
- Savitribai Phule Pune University (IN)
- Academy of Scientific and Innovative Research (IN)
Publication Details
- Journal
- ACS Sustainable Resource Management
- Published
- 2025-01-27
- DOI
- https://doi.org/10.1021/acssusresmgt.4c00259
- Citations
- 2
- Primary Topic
- Supercapacitor Materials and Fabrication
- Type
- article
- Field-Weighted Citation Impact
- 0.85
Funders
- Council of Scientific and Industrial Research, India