KO<sup><i>t</i></sup>Bu-Promoted [3 + 2] Cycloaddition of Dimethyl Sulfoxide with Fullerenes
KO<sup><i>t</i></sup>Bu-promoted [3 + 2] cycloaddition of dimethyl sulfoxide (DMSO) with fullerenes has been developed for facile and efficient one-pot synthesis of 1,2,3,4-cyclic sulfoxide-fused [60]/[70]fullerene dihydrides, which offers a versatile platform for the site-selective preparation of various fullerene multiadducts with a wide range of functional groups. The utility of these tetra-functionalized fullerenes is demonstrated by the successful application as electron-transport materials in perovskite solar cells.
Authors
- Wen-Bin Ma
- Bin‐Wen Chen
- Jun Xuan (ORCID: https://orcid.org/0000-0003-0578-9330)
- Lin‐Long Deng (ORCID: https://orcid.org/0000-0002-8588-1825)
- Su‐Yuan Xie (ORCID: https://orcid.org/0000-0003-2370-9947)
- Jinying Liu (ORCID: https://orcid.org/0000-0003-4197-3266)
- Fei Li (ORCID: https://orcid.org/0000-0001-9822-7526)
Institutions
- Anhui University (CN)
- Institute of Technology of Cambodia (KH)
- Xiamen University (CN)
- Collaborative Innovation Center of Chemistry for Energy Materials (CN)
- Xiamen University of Technology (CN)
Publication Details
- Journal
- Organic Letters
- Published
- 2025-01-27
- DOI
- https://doi.org/10.1021/acs.orglett.4c04802
- Citations
- 1
- Primary Topic
- Fullerene Chemistry and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.94
Funders
- National Natural Science Foundation of China
- Anhui Provincial Department of Education