Nitroacetonitrile in Reactions with Enones

Reactions of nitroacetonitrile with enones, depending on the structure of the latter, lead to the formation of either condensation products at the carbonyl group or Michael adducts, which are capable of undergoing further intra- and intermolecular transformations. The structure of the synthesized products was established using 1H, 13C{1H} NMR, and IR spectroscopy.

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Publication Details

Journal
Russian Journal of General Chemistry
Published
2024-12-01
DOI
https://doi.org/10.1134/s1070363224120090
Primary Topic
Chemical Reaction Mechanisms
Type
article
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article

Nitroacetonitrile in Reactions with Enones

Р. И. Байчурин, L. V. Baichurina, A. V. Fel’gendler, O. B. Vuks
Russian Journal of General Chemistry
Chemical Reaction Mechanisms
article

Nitroacetonitrile in Reactions with Enones

Р. И. Байчурин, L. V. Baichurina, A. V. Fel’gendler, O. B. Vuks
article en

Abstract

Reactions of nitroacetonitrile with enones, depending on the structure of the latter, lead to the formation of either condensation products at the carbonyl group or Michael adducts, which are capable of undergoing further intra- and intermolecular transformations. The structure of the synthesized products was established using 1H, 13C{1H} NMR, and IR spectroscopy.

Russian Journal of General ChemistryVol. 94(12)
S. M. Kirov Military Medical Academy (RU), Herzen University (RU)
Openalex Percentile: Top 81%
Chemical Reaction Mechanisms
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