Fluid infiltration along reactive porosity networks at the subduction interface: Evidence from the eclogite-facies Erro-Tobbio Unit (Ligurian Alps)

In subduction zones, seismicity and rock rheology are strongly influenced by the presence of fluids. However, the mechanisms governing fluid extraction and transport along the subduction interface are still debated. The meta-peridotite of the Erro-Tobbio Unit (Ligurian Alps) records fluid-rock interaction and associated deformation that occurred at intermediate subduction depths. Fluid pathways are represented by reaction bands of metamorphic olivine (Ol 2 ) and Ti-clinohumite, formed by the breakdown of brucite (Brc) and antigorite (Atg) at 1.8–2.5 GPa and 500–650 °C. Field and microstructural analyses allowed the role of deformation in the development of ORBs to be assessed. In-situ determination of trace elements by LA-ICP-MS allowed the scale of fluid circulation along reaction-induced channels to be constrained. The reaction bands occur within both meta-peridotite cores and wrapping horizons of prograde antigorite mylonites. The meta-peridotite shows two main sets of reaction bands: Set 1 , oriented at high angle to the bounding mylonites, and Set 2 , trending N-S, parallel to the mylonites (where only Set 2 is present). A decrease in spacing between reaction bands of Set 2 highlights a strain gradient from the undeformed meta-peridotite cores to the mylonites. This gradient, associated with oriented growth of Ol 2 in the mylonites, suggests that the reaction bands developed during mylonitization. Brc relics mostly localized within the reaction bands indicate that formation of Ol 2 was originally controlled by the Brc distribution. Such channel networks have been described in previous works as the result of channel-forming reactive porosity related to initial breakdown of thermodynamically favoured domains. The formation of the reaction bands may be therefore related to formation of low-Si fluids in Brc-rich areas, which triggered Atg breakdown and formation of porosity by flowing along planes consistent with the stress field. Later stage, Al-free serpentine (Atg + chrysotile/lizardite) locally replaces Ol 2 along a pervasive network of microcracks exploiting the reactive sites of Set 1 - Set 2 structures. An enrichment in fluid-mobile elements (As, Sb, Ba, W, Li, B) in prograde Ol 2 and later-stage Al-free serpentine provides evidence of two stages of infiltration of slab-derived fluids, indicating open-system conditions during eclogite-facies deformation and during retrogression. We speculate that the Erro-Tobbio Unit was subducted at an early stage of Adria-Europe convergence and settled atop the interface within the deep slow-earthquakes depth range, above the continuously under-riding and dehydrating Alpine slab. In this environment, the Erro-Tobbio Unit was affected by intense chemical exchange due to fluid fluxing from the underlying subducting units. • Various sets of olivine-bearing dehydration bands formed during subduction in Erro-Tobbio meta-peridotite and serpentinite. • The dehydration bands were later exploited by low-temperature serpentinization and fluid infiltration during exhumation. • FMEs (B, Li, As, Sb, Ba, Sr) indicate two stages of infiltration of slab-derived fluids during subduction and exhumation. • Erro-Tobbio was subducted early during Adria-Europe convergence and fluxed by fluids released by the under-riding slab.