Reaction of the [B10H11]– Anion with Dicyanostilbenes
In this work, the interaction of the closo-decaborate anion with a series of substituted dicyanostilbenes was studied. A range of new derivatives of the composition [B10H9R]–, where R is a phenanthrenedicyan substituent with substituents at positions 1 and 10, was obtained. Optimal reaction conditions were selected. To increase the stability of the target compounds, amidine derivatives were synthesized by reacting the obtained nitrile derivatives of the closo-decaborate anion with ammonia in an aqueous-alcoholic medium. The composition and structure of the obtained compounds were determined using multinuclear NMR spectroscopy, mass spectrometry, and IR spectroscopy.
Authors
- К. Yu. Zhizhin (ORCID: https://orcid.org/0000-0002-4475-124X)
- N. K. Neumolotov (ORCID: https://orcid.org/0000-0002-8786-624X)
- А. P. Zhdanov
- Alexander V. Yakimansky (ORCID: https://orcid.org/0000-0002-8770-1453)
- Н. Т. Кузнецов (ORCID: https://orcid.org/0000-0002-2562-6427)
- А. Yu. Bykov
- Н. А. Селиванов (ORCID: https://orcid.org/0000-0001-7426-5982)
- В. В. Воинова (ORCID: https://orcid.org/0000-0002-4765-7304)
- Tatiana G. Chulkova (ORCID: https://orcid.org/0000-0001-6997-627X)
- Anton A. Yakimanskiy (ORCID: https://orcid.org/0009-0005-4444-2358)
Institutions
- Kurchatov Institute (RU)
- NS Kurnakova Institute of General and Inorganic Chemistry (RU)
- Petersburg Nuclear Physics Institute (RU)
Publication Details
- Journal
- Russian Journal of Inorganic Chemistry
- Published
- 2024-12-01
- DOI
- https://doi.org/10.1134/s0036023624603532
- Primary Topic
- Boron Compounds in Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00