Studying the Electrochemical Behavior of a Smooth Gold Electrode in a Solution of Bridged 1,2,4-Trioxalane in Acetonitrile
Cyclic voltammetry and gravimetry are used to study the behavior of a smooth gold electrode in a medium of bridged 1,2,4-trioxalane in acetonitrile. It is found that the peroxide bond in the molecule of bridged 1,2,4-trioxalane is reduced on the surface of the electrode during the cathodic process, with the subsequent formation of a diketone fragment. The formation of colloidal gold particles is detected during anodic oxidation.
Authors
- А. М. Скундин (ORCID: https://orcid.org/0000-0001-7627-5703)
- M. V. Polyakov (ORCID: https://orcid.org/0009-0007-2861-9074)
- Ivan A. Yaremenko (ORCID: https://orcid.org/0000-0003-1068-9051)
- Peter S. Radulov (ORCID: https://orcid.org/0000-0003-2653-0395)
- M. D. Vedenyapina
Institutions
- Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences (RU)
- N.D. Zelinsky Institute of Organic Chemistry (RU)
Publication Details
- Journal
- Russian Journal of Physical Chemistry A
- Published
- 2024-12-01
- DOI
- https://doi.org/10.1134/s0036024424702443
- Citations
- 2
- Primary Topic
- Electrochemical Analysis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.34