Chemically Modified Pineapple Leaf Fibre as a Filler of Polyurethane-Based Composites

Pineapple leaf fibres represent a biodegradable raw material sourced from renewable resources whose use contributes to reducing the carbon footprint and limiting the amount of waste generated. Their potential applications can effectively decrease the industry's dependence on plastics and support sustainable development, which should accompany the production of modern materials. In this study, polyurethane-based composites reinforced with various types of natural cellulose fillers were developed and investigated. Microcrystalline cellulose and unmodified and chemically modified pineapple leaf fibres were used as reinforcements. The mechanical and thermal properties of the produced materials were determined and compared. The results of the tests indicated that both microcrystalline cellulose and pineapple leaf fibres contributed to a reduction in the mechanical properties of polyurethane. A varying impact of fillers on the Young's modulus of the biocomposites was observed. The presence of natural modifiers influenced an increase in the melting temperature of the composite compared to the pure polyurethane. Integration of natural pineapple fibres into composite represents a step toward a more sustainable future, combining economic benefits with environmental care. The mechanical characteristics of composite materials were enhanced by modified fibres, compared to their unmodified counterparts. This improvement comes from the unique structural properties of the modified fibres. When polyurethane (PU) is used as the matrix material, it effectively fills the interfibrillar voids, creating a more cohesive bond between the components.