Experimental Simulation of Pyrolysis Products Recycling via Detonation

Earlier the efficiency of a stand in form of the open-end Π-shape tube for deflagration-to-detonation transition (DDT) of propane—air mixtures at normal pressure was shown. In this work, the study of the DDT is extended to the mixtures modeling real gaseous pyrolysis products of polyethylene and rubber-containing industrial and domestic waste. Modeling mixtures with air contain Н2, СН4, С2Н6, С2Н4, С3Н8 and С3Н6 in stoichiometric or lean concentration based on the experimental data presented in the literature. Conditions when the DDT can be reached (stand design, initial pyrolysis products mixture concentration) are defined. Measurements of the temperature of the mixture passed through the stand in addition to dynamic measurements allow to define the character of the processing: DDT, fast or slow deflagration. It has been shown that propane as a model fuel may be used instead of pyrolysis gases mixtures when studying DDT. The results supposed to be helpful for the waste recycling industrial setups engineering.

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Publication Details

Journal
Russian Journal of Physical Chemistry B
Published
2024-12-01
DOI
https://doi.org/10.1134/s1990793124701379
Primary Topic
Combustion and Detonation Processes
Type
article
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article

Experimental Simulation of Pyrolysis Products Recycling via Detonation

É. K. Anderzhanov, A. N. Ivantsov, А. М. Tereza, V. N. Mikhalkin et al.
Russian Journal of Physical Chemistry B
Combustion and Detonation Processes
article

Experimental Simulation of Pyrolysis Products Recycling via Detonation

É. K. Anderzhanov, A. N. Ivantsov, А. М. Tereza, V. N. Mikhalkin, I. V. Bilera, S. P. Medvedev, S. V. Khomik, G. L. Agafonov
article en

Abstract

Earlier the efficiency of a stand in form of the open-end Π-shape tube for deflagration-to-detonation transition (DDT) of propane—air mixtures at normal pressure was shown. In this work, the study of the DDT is extended to the mixtures modeling real gaseous pyrolysis products of polyethylene and rubber-containing industrial and domestic waste. Modeling mixtures with air contain Н2, СН4, С2Н6, С2Н4, С3Н8 and С3Н6 in stoichiometric or lean concentration based on the experimental data presented in the literature. Conditions when the DDT can be reached (stand design, initial pyrolysis products mixture concentration) are defined. Measurements of the temperature of the mixture passed through the stand in addition to dynamic measurements allow to define the character of the processing: DDT, fast or slow deflagration. It has been shown that propane as a model fuel may be used instead of pyrolysis gases mixtures when studying DDT. The results supposed to be helpful for the waste recycling industrial setups engineering.

Russian Journal of Physical Chemistry BVol. 18(6)
Semenov Institute of Chemical Physics (RU), A.V. Topchiev Institute of Petrochemical Synthesis (RU)
Openalex Percentile: Top 57%
Combustion and Detonation Processes
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