Smart-Alloying for tailored microstructures in laser-based metal additive manufacturing

Smart-Alloying enables local modification of the chemical composition of metallic components within additive manufacturing processes. This new method represents an innovative process for localized grading of metallic materials in laser-based additive manufacturing. Smart-Alloying involves applying nanoparticulate alloying elements onto the surfaces of additive manufactured components in precise doses using suspensions. The method is shown here using laser powder bed fusion as an example. By coating the base material powder and exposing it to the laser source, localized modifications in chemical composition and altered properties can be achieved. Using a chromium-rich ferritic stainless steel, significant alterations in the fundamental microstructure are attained through localized re-alloying of carbon. Investigation utilizing focused ion beam-scanning electron microscope elucidates the evolution of increasing carbon content within the re-alloyed area. Next to the formation of chromium-rich carbides and ultrafine regions of needle-like martensite, retained austenite could be made visible. Transmission electron microscopy investigations proved these findings and revealed mainly α-ferritic microstructure with small γ-austenitic grains as well as the presence of chromium-rich carbides on the main grain boundaries. The completely renewed microstructure is then further modified using secondary exposures of the laser source. Under the influence of the subsequent melting process, there is an increasing distribution of the re-alloyed carbon, resulting in a completely new structure of a line-shaped duplex microstructure. The integration of secondary exposure introduces a completely novel aspect, offering the potential to merge localized grading via Smart-Alloying with targeted applications of laser parameters.