Distinct creep regimes of methane hydrates predicted by a monatomic water model

The power-law creep properties of methane hydrates were measured experimentally two decades ago, but their microscopic explanation is still missing. Here we show, using molecular dynamics simulations spanning almost 2 orders of magnitude of stresses and 3 orders of magnitude of strain rates, that such power-law creep emerges in molecular dynamics simulations of polycrystalline methane hydrates using a monatomic water model, suggesting that only simplified molecular interactions and the concept of a hydrate polycrystal are needed for such power-law creep behavior to emerge. Damage patterns post-creep suggest that hydrates are strong because damage only occurs on crystal surfaces.

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Publication Details

Journal
Physical Review Research
Published
2025-01-09
DOI
https://doi.org/10.1103/physrevresearch.7.l012007
Citations
2
Primary Topic
Methane Hydrates and Related Phenomena
Type
article
Field-Weighted Citation Impact
1.72

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article

Distinct creep regimes of methane hydrates predicted by a monatomic water model

Pinqiang Cao, Henrik Andersen Sveinsson
2 citations
Physical Review Research
Methane Hydrates and Related Phenomena
1.72
article

Distinct creep regimes of methane hydrates predicted by a monatomic water model

Pinqiang Cao, Henrik Andersen Sveinsson
article en
2 citations

Abstract

The power-law creep properties of methane hydrates were measured experimentally two decades ago, but their microscopic explanation is still missing. Here we show, using molecular dynamics simulations spanning almost 2 orders of magnitude of stresses and 3 orders of magnitude of strain rates, that such power-law creep emerges in molecular dynamics simulations of polycrystalline methane hydrates using a monatomic water model, suggesting that only simplified molecular interactions and the concept of a hydrate polycrystal are needed for such power-law creep behavior to emerge. Damage patterns post-creep suggest that hydrates are strong because damage only occurs on crystal surfaces.

Physical Review ResearchVol. 7(1)
University of Oslo (NO), Wuhan University of Science and Technology (CN)
National Natural Science Foundation of China, Norges Forskningsråd
Clean water and sanitation
Openalex Percentile: Top 20%
Methane Hydrates and Related Phenomena
1.72
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