Cu-histidinyl catalysts for mild and efficient propargylic alcohol carboxylation with CO2
Propargylic alcohol cyclizing carboxylation with CO 2 at atmospheric pressure was catalyzed by a nanocluster, Cu(I) 4 (histidinyl) 4 Ga(I)I. excess His, abbreviated Cu-Ga, at 50°C, providing α-alkylidene cyclic carbonates in good yields. The nanocluster Cu-Ga supported in ZIF-8, noted Cu-Ga/ZIF-8, heterogeneously catalyzed this cyclizing carboxylation of various terminal propargyl alcohols and was recycled five time without significant yield decrease. CO2 activation with non-noble Cu-Ga catalyst Catalysis of propargyl alcohol carboxylation Synthesis of α-alkylidene cyclic carbonates Synergistic Cu-Ga-ZIF-8 catalysis ZIF-8 stabilizes Cu-Ga catalyst for recycling
Authors
- Guilherme Mateus Bousada (ORCID: https://orcid.org/0000-0002-3522-8668)
- Lionel Salmon (ORCID: https://orcid.org/0000-0002-8064-8960)
- Philippe Hapiot (ORCID: https://orcid.org/0000-0002-6730-3570)
- Haizhu Yu (ORCID: https://orcid.org/0000-0001-8259-6466)
- Sergio Moya (ORCID: https://orcid.org/0000-0002-7174-1960)
- Nathalie Daro (ORCID: https://orcid.org/0000-0002-3707-9686)
- Didier Astruc (ORCID: https://orcid.org/0000-0002-2258-3126)
- Tiansheng Wang (ORCID: https://orcid.org/0000-0001-6472-4719)
- Jean‐René Hamon (ORCID: https://orcid.org/0000-0003-4630-4096)
- Jean‐Luc Pozzo
- Yue Liu (ORCID: https://orcid.org/0000-0002-9117-940X)
- Ahmed Subrati
Institutions
- Centre National de la Recherche Scientifique (FR)
- Anhui University (CN)
- Université de Bordeaux (FR)
- Institut des Sciences Moléculaires (FR)
- CIC biomaGUNE (ES)
- Institut des Sciences Chimiques de Rennes (FR)
- Institut de Chimie de la Matière Condensée de Bordeaux (FR)
- Institut Polytechnique de Bordeaux (FR)
- Institut de Mathématiques de Bordeaux (FR)
- Université de Rennes (FR)
Publication Details
- Journal
- Coordination chemistry research.
- Published
- 2025-01-09
- DOI
- https://doi.org/10.1016/j.cocr.2025.100005
- Citations
- 1
- Primary Topic
- Carbon dioxide utilization in catalysis
- Type
- article
- Field-Weighted Citation Impact
- 0.70
Funders
- National Natural Science Foundation of China
- Coordenação de Aperfeiçoamento de Pessoal de Nível Superior
- Centre National de la Recherche Scientifique
- Natural Science Foundation of Anhui Province