Fabrication of vertical structure type bimetallic MOF@ biomass aerogels for efficient CO2 capture and separation

Effectively capturing carbon dioxide (CO 2 ) is crucial for environmental protection. In this research, we synthesized a composite aerogel (CSA-n) by integrating a bimetallic metal-organic framework (Mg/Co-MOF-74) with biomass materials (cellulose/chitosan) using an in situ mineralization approach. This composite aerogel exhibited enhanced CO 2 adsorption capabilities than pure biomass aerogel. At 298 K and 100 KPa, the CO 2 adsorption capacity of CSA-3 reached 6.4 mmol/g, an increase of 16.4% compared to pure MOF. The significant improvement of CO 2 uptakes could be attributed to the more complex pore structure of the composite aerogel compared to pure MOF. Additionally, simulations based on the ideal adsorption solution theory (IAST) showed that the separation factors of CSA-3 for CO 2 /N 2 and CO 2 /CH 4 gas mixtures were 594.3 and 43.4, respectively. Furthermore, the composite aerogel exhibited excellent cyclic stability. After 10 cycles, the CO 2 adsorption capacity of CSA-3 remained at 96.8%. The results suggest that this bimetallic metal-organic framework @biomass hybrid aerogel holds great potential for CO 2 adsorption and separation applications.