<i>N</i>-Monoarylated dihydrophenazines in reduced and oxidized states as efficient organo-photocatalysts
In this work, the synthesis of an <i>N</i>-monoarylated dihydrophenazine is reported together with its interconversion to its oxidized mono-cationic form. While the reduced state was employed for the dechlorination of aromatic substrates, the oxidized mono-cationic one was exploited for the formation of C-N bonds between aryl rings and azoles, which was achieved with high yields and very low catalyst loadings (down to 0.5 mol%).
Authors
- Jacopo Dosso (ORCID: https://orcid.org/0000-0003-4173-3430)
- Maurizio Prato (ORCID: https://orcid.org/0000-0002-8869-8612)
Institutions
- Ikerbasque (ES)
- University of Trieste (IT)
- CIC biomaGUNE (ES)
- National Interuniversity Consortium of Materials Science and Technology (IT)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d4cc06499b
- Citations
- 3
- Primary Topic
- Radical Photochemical Reactions
- Type
- article
- Field-Weighted Citation Impact
- 2.81
Funders
- Consorzio Interuniversitario Nazionale per la Scienza e Tecnologia dei Materiali
- Ministero dell’Istruzione, dell’Università e della Ricerca
- Università degli Studi di Trieste