Fiber-Optic Photoacoustic Gas Microprobe Based on Linear Spot-Type Multipass Cell

A linear spot-type multipass cell-enhanced fiber-optic photoacoustic gas microprobe is proposed. To further reduce the volume of the gas chamber and enhance the photoacoustic signal, we designed the cross section of the photoacoustic tube as a slit with a height of 10 mm and a width of 1.5 mm. The volume of the gas chamber is only 210 μL. Through theoretical analysis and multiphysical field simulation, the photoacoustic intensity of the slit cross section is more than 6 times that of traditional circular cross section. A cantilever beam is integrated into the photoacoustic microprobe and forms a Fabry-Perot (FP) interferometer with an optical fiber, achieving enhanced photoacoustic detection. By adjusting the angle of the collimator, the light passes through the photoacoustic cell 26 times, and 13 linear spots are formed on the reflecting surface. The photoacoustic signal with multiple linear reflections is 12.4 times that of a single reflection. The gas enters the sensor in a freely diffused manner, and the response time of the sensing system is 54 s. When the averaging time is 400 s, the detection limit of the designed sensor for acetylene gas reaches 1.5 ppb. The minimum detectable absorption coefficient (α<sub>min</sub>) and the normalized noise equivalent absorption coefficient (NNEA) are 1.7 × 10<sup>-8</sup> cm<sup>-1</sup> and 1.9 × 10<sup>-9</sup> Wcm<sup>-1</sup>/Hz<sup>1/2</sup>, respectively.

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Publication Details

Journal
Analytical Chemistry
Published
2025-01-09
DOI
https://doi.org/10.1021/acs.analchem.4c05486
Citations
19
Primary Topic
Spectroscopy and Laser Applications
Type
article
Field-Weighted Citation Impact
14.37

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article

Fiber-Optic Photoacoustic Gas Microprobe Based on Linear Spot-Type Multipass Cell

Zhaodong Zhang, Yufu Xu, Heng Wang, Ke Chen et al.
19 citations
Analytical Chemistry
Spectroscopy and Laser Applications
14.37
article

Fiber-Optic Photoacoustic Gas Microprobe Based on Linear Spot-Type Multipass Cell

Zhaodong Zhang, Yufu Xu, Heng Wang, Ke Chen, Xinyu Zhao, Jingya Zhang
article en
19 citations

Abstract

A linear spot-type multipass cell-enhanced fiber-optic photoacoustic gas microprobe is proposed. To further reduce the volume of the gas chamber and enhance the photoacoustic signal, we designed the cross section of the photoacoustic tube as a slit with a height of 10 mm and a width of 1.5 mm. The volume of the gas chamber is only 210 μL. Through theoretical analysis and multiphysical field simulation, the photoacoustic intensity of the slit cross section is more than 6 times that of traditional circular cross section. A cantilever beam is integrated into the photoacoustic microprobe and forms a Fabry-Perot (FP) interferometer with an optical fiber, achieving enhanced photoacoustic detection. By adjusting the angle of the collimator, the light passes through the photoacoustic cell 26 times, and 13 linear spots are formed on the reflecting surface. The photoacoustic signal with multiple linear reflections is 12.4 times that of a single reflection. The gas enters the sensor in a freely diffused manner, and the response time of the sensing system is 54 s. When the averaging time is 400 s, the detection limit of the designed sensor for acetylene gas reaches 1.5 ppb. The minimum detectable absorption coefficient (α<sub>min</sub>) and the normalized noise equivalent absorption coefficient (NNEA) are 1.7 × 10<sup>-8</sup> cm<sup>-1</sup> and 1.9 × 10<sup>-9</sup> Wcm<sup>-1</sup>/Hz<sup>1/2</sup>, respectively.

Analytical ChemistryVol. 97(2)
Dalian University of Technology (CN), Dalian University (CN)
National Natural Science Foundation of China, Natural Science Foundation of Liaoning Province, Fundamental Research Funds for the Central Universities
Affordable and clean energy
Openalex Percentile: Top 1%
Spectroscopy and Laser Applications
14.37
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