Zirconium <i>vs.</i> hafnium: a comparative study of mesoporous MOF stability
A wide range of mesoporous Zr and Hf metal-organic frameworks (MOFs), namely MIP-206, MOF-808, and NU-1000, as well as the microporous UiO-66, were systematically investigated and compared in terms of thermal and chemical stability. The holistic effects of metal type (Zr <i>vs.</i> Hf), linker type (small and rigid <i>vs.</i> large and flexible), and framework topology (2D <i>vs.</i> 3D) on the overall framework stability were investigated.
Authors
- J. Requies (ORCID: https://orcid.org/0000-0002-9764-8377)
- Orysia Zaremba (ORCID: https://orcid.org/0000-0002-6855-5518)
- Subhajit Dutta (ORCID: https://orcid.org/0000-0003-1440-7808)
- Jacopo Andreo (ORCID: https://orcid.org/0000-0002-8153-5802)
- Stefan Wuttke (ORCID: https://orcid.org/0000-0002-6344-5782)
Institutions
- University of the Basque Country (ES)
- United Arab Emirates University (AE)
- Basque Center for Materials, Applications and Nanostructures (ES)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d4cc03103b
- Citations
- 3
- Primary Topic
- Metal-Organic Frameworks: Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 1.61
Funders
- Human Frontier Science Program
- Ministerio de Ciencia, Tecnología e Innovación Productiva
- European Regional Development Fund