A metal–organic framework with mixed electron donor and electron acceptor ligands for efficient lithium-ion storage
Electron donor tetrathiafulvalene (TTF) and electron acceptor naphthalene diimide (NDI) derivatives were used to synthesize a 3D Zn-TTF/NDI-MOF. Multiple redox active sites and charge transfer endow the pristine MOF anode with excellent rate behavior and long term cycling performance (with an average specific capacity of 956 mA h g<sup>-1</sup> at 1 A g<sup>-1</sup> over 600 cycles). This study highlights the great potential of elaborately-designed MOFs for developing efficient anode materials.
Authors
- Jun-Die Zhang
- Wei Liu (ORCID: https://orcid.org/0000-0003-2940-7755)
- Ziyi Wang (ORCID: https://orcid.org/0009-0000-0729-4740)
- Ruonan Wang (ORCID: https://orcid.org/0000-0002-5837-6911)
- Yu-Chuan Tan
- Qin‐Yu Zhu (ORCID: https://orcid.org/0000-0003-1864-1175)
Institutions
- Soochow University (CN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d4cc05567e
- Citations
- 3
- Primary Topic
- Advancements in Battery Materials
- Type
- article
- Field-Weighted Citation Impact
- 2.19
Funders
- National Natural Science Foundation of China