Structural defects and heat capacity of iodide cadmium

In this work, a creation of donor-acceptor (DA) complexes (trimmers) in highly anisotropic layered crystals of CdI2 is analyzed. The impact of DA complexes on lattice dynamics is investigated. Experimental studies of the temperature dependence of the heat capacity of crystals were applied and the significant impact of impurities in the crystal matrix was revealed. Einstein temperatures for samples of CdI2, CdI2 with Cu, CdI2 with Cu, Au were calculated for the first time and the consistency of the proposed model with theory and experiment is demonstrated.

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Publication Details

Journal
Low Temperature Physics
Published
2025-01-01
DOI
https://doi.org/10.1063/10.0034643
Citations
3
Primary Topic
Solid-state spectroscopy and crystallography
Type
article
Field-Weighted Citation Impact
1.55
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article

Structural defects and heat capacity of iodide cadmium

B. Seredyuk, N. K. Tovstyuk, M. Orendáč, R. Tarasenko et al.
3 citations
Low Temperature Physics
Solid-state spectroscopy and crystallography
1.55
article

Structural defects and heat capacity of iodide cadmium

B. Seredyuk, N. K. Tovstyuk, M. Orendáč, R. Tarasenko, Mykola Rudka, Mariana Karkulovska
article en
3 citations

Abstract

In this work, a creation of donor-acceptor (DA) complexes (trimmers) in highly anisotropic layered crystals of CdI2 is analyzed. The impact of DA complexes on lattice dynamics is investigated. Experimental studies of the temperature dependence of the heat capacity of crystals were applied and the significant impact of impurities in the crystal matrix was revealed. Einstein temperatures for samples of CdI2, CdI2 with Cu, CdI2 with Cu, Au were calculated for the first time and the consistency of the proposed model with theory and experiment is demonstrated.

Low Temperature PhysicsVol. 51(1)
University of Pavol Jozef Šafárik (SK), Hetman Petro Sahaidachnyi National Army Academy (UA), FZU ‒ Institute of Physics of the Academy of Sciences of the Czech Republic (CZ), Lviv Polytechnic National University (UA)
Clean water and sanitation
Openalex Percentile: Top 20%
Solid-state spectroscopy and crystallography
1.55
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Structural defects and heat capacity of iodide cadmium — B. Seredyuk, N. K. Tovstyuk, et al. · Low Temperature Physics (2025) | TGRS Research Map | TGRS