Green synthesis of zinc oxide nanoparticles using Padina pavonica extract for efficient photocatalytic removal of methylene blue

Dye-laden wastewater poses a significant environmental and health threat. This study investigated the potential of green-synthesized zinc oxide nanoparticles (ZnO NPs), derived from Padina pavonica brown algae extract, for the removal of methylene blue (MB) dye. The hypothesis was that utilizing algal extract for ZnO NP synthesis would enhance adsorption capacity and photocatalytic activity for dye removal. The synthesized ZnO NPs, characterized by Infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM), Energy Dispersive X-ray Spectroscopy (EDX) and Zeta Potential, demonstrated high adsorption capacity (Qm = 192.308 mg g^-1) and excellent removal efficiency (> 98%) for MB at low dye concentrations. Langmuir isotherm and pseudo-second-order kinetic models best fit the experimental data, suggesting monolayer adsorption and chemisorption as the primary mechanisms. Notably, the green ZnO NPs exhibited greater photocatalytic activity under direct sunlight irradiation compared to other light sources. Additionally, these nanoparticles displayed antimicrobial properties against various bacteria, indicating potential for water disinfection. This research offers a sustainable and environmentally friendly approach for wastewater treatment utilizing green ZnO NPs for efficient dye removal and potential water disinfection applications.