Scope and mechanistic insight into the chemistry of cyanocarbenes derived from alkynyl triazenes by UV irradiation
Cyanocarbenes derived from alkynyl triazenes are investigated with respect to their reactivity with olefins and alkynes to produce cyclopropanes and cyclopropenes with high selectivity, offering eco-friendly, cost-effective synthetic advantages.
Authors
- Alexandra V. Mackenroth (ORCID: https://orcid.org/0009-0006-8394-5625)
- Martin C. Dietl (ORCID: https://orcid.org/0000-0002-6115-4674)
- Matthias Rudolph (ORCID: https://orcid.org/0000-0002-0331-8394)
- Andreas Dreuw (ORCID: https://orcid.org/0000-0002-5862-5113)
- Elena Michel
- Frank Röminger
- Linus Bjarne Dittmer (ORCID: https://orcid.org/0009-0008-9480-1250)
- Melina Maag
Institutions
- King Abdulaziz University (SA)
- Heidelberg University (DE)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2024-12-30
- DOI
- https://doi.org/10.1039/d4qo02023e
- Citations
- 5
- Primary Topic
- Chemical Reactions and Mechanisms
- Type
- article
- Field-Weighted Citation Impact
- 2.22