Phenylphosphonic acid corroles: corroles that link and bind
We report herein the synthesis and full spectroscopic characterization of two A<sub>2</sub>B-corrole phosphonic acids. Thanks to the presence of a phosphonic acid functional group at the 10-<i>meso</i>-position, the corroles were covalently linked to the hexanuclear Zr clusters of a PCN-222 metal-organic framework (MOF). After the insertion of cobalt into the corrole macrocycle, the metal complexes are able to bind small volatile molecules such as carbon monoxide (CO). Interestingly, the resulting doped porous materials were used for selective detection of CO, with excellent selectivity for CO <i>vs.</i> CO<sub>2</sub>, N<sub>2</sub>, and O<sub>2</sub>.
Authors
- Laurie André (ORCID: https://orcid.org/0000-0002-9574-9617)
- Yoann Rousselin (ORCID: https://orcid.org/0000-0002-6702-1303)
- Nicolas Desbois (ORCID: https://orcid.org/0000-0002-1156-4608)
- Claude P. Gros (ORCID: https://orcid.org/0000-0002-6966-947X)
- Stéphane Brandès (ORCID: https://orcid.org/0000-0001-6923-1630)
- Margerie Loze
- Gaëlle Divoux
Institutions
- Centre National de la Recherche Scientifique (FR)
- Université de Bourgogne (FR)
- Institut de Chimie (FR)
Publication Details
- Journal
- Dalton Transactions
- Published
- 2024-12-30
- DOI
- https://doi.org/10.1039/d4dt03197k
- Citations
- 1
- Primary Topic
- Porphyrin and Phthalocyanine Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.12
Funders
- European Commission
- Agence Nationale de la Recherche
- Université de Bourgogne
- Centre National de la Recherche Scientifique
- Conseil régional de Bourgogne-Franche-Comté
- European Regional Development Fund