Determination of performance properties of galvanic coatings based on cobalt

Abstract. Problem. An effective solution to the problem of the durability of construction materials is the application of protective coatings, which allow tosignificantly expand the scope of use and service life of products. The purpose of the work was to determine the performance characteristics of electrolytic coatings with Co-Ni-Zr alloy, namely adhesion and microhardness. Methodology The microhardness of the coatings was determined by the indentation depth of the diamond pyramid. Coating adhesion was determined by the fracture method. The chemical composition of the obtained coatings was determined by the X-ray fluorescence method using the SPRUT portable spectrometer. The analysis was carried out at least in 3 points with subsequent averaging of the obtained values. Electrodeposition was carried out with a unipolar current in stationary and pulsed modes (ti/tр=2/2) while varying the current density. Originality. There are no signs of delamination of the coatings on the sandpaper, which emphasizes strong adhesion to the base. The results of metallographic studies proved that Co-Ni-Zr coatings have good adhesion to the substrate material and retain it under mechanical loads. The highest value of microhardness – 850.0 MPa was obtained in the galvanostatic mode at i = = 6 A/dm2, while the zirconium content in the alloy is 1.5 wt.%. From the results of the experiments, it can be concluded that the zirconium content does not affect the microhardness of the Co-Ni-Zr coating. When the current density increases, the microhardness of the deposit decreases, which can be explained by reaching the maximum density of the deposition current. The optimal deposition current density for the galvanostatic mode is 6 A/dm2, pulsed 6 A/dm2 for obtaining coatings with high microhardness

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Publication Details

Journal
Bulletin of Kharkov National Automobile and Highway University
Published
2024-12-26
DOI
https://doi.org/10.30977/bul.2219-5548.2024.107.0.48
Primary Topic
Surface Treatment and Coatings
Type
article
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article

Determination of performance properties of galvanic coatings based on cobalt

Николай Дмитриевич Сахненко, Tetiana Nenastina
Bulletin of Kharkov National Automobile and Highway University
Surface Treatment and Coatings
article

Determination of performance properties of galvanic coatings based on cobalt

Николай Дмитриевич Сахненко, Tetiana Nenastina
article en

Abstract

Abstract. Problem. An effective solution to the problem of the durability of construction materials is the application of protective coatings, which allow tosignificantly expand the scope of use and service life of products. The purpose of the work was to determine the performance characteristics of electrolytic coatings with Co-Ni-Zr alloy, namely adhesion and microhardness. Methodology The microhardness of the coatings was determined by the indentation depth of the diamond pyramid. Coating adhesion was determined by the fracture method. The chemical composition of the obtained coatings was determined by the X-ray fluorescence method using the SPRUT portable spectrometer. The analysis was carried out at least in 3 points with subsequent averaging of the obtained values. Electrodeposition was carried out with a unipolar current in stationary and pulsed modes (ti/tр=2/2) while varying the current density. Originality. There are no signs of delamination of the coatings on the sandpaper, which emphasizes strong adhesion to the base. The results of metallographic studies proved that Co-Ni-Zr coatings have good adhesion to the substrate material and retain it under mechanical loads. The highest value of microhardness – 850.0 MPa was obtained in the galvanostatic mode at i = = 6 A/dm2, while the zirconium content in the alloy is 1.5 wt.%. From the results of the experiments, it can be concluded that the zirconium content does not affect the microhardness of the Co-Ni-Zr coating. When the current density increases, the microhardness of the deposit decreases, which can be explained by reaching the maximum density of the deposition current. The optimal deposition current density for the galvanostatic mode is 6 A/dm2, pulsed 6 A/dm2 for obtaining coatings with high microhardness

Bulletin of Kharkov National Automobile and Highway University(107)
Openalex Percentile: Top 75%
Surface Treatment and Coatings
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