Information hidden in the state change of a gas obtained from the theoretical integrations of the partial derivatives

The calculations of the change in the gas state are critical in most engineering applications. Generally, engineers and scientists use Boyle-Charles-Gay Lussac's (B-C-G) law of P1V1/T1 = P2V2/T2 to calculate pressure (P), volume (V), and temperature (T) of gases and vapors. Although the B-C-G law provides accurate gas properties of P-V-T, it does not give any specific information about the process of a state change by which gases and vapors change their state. In this study, the authors performed, for the first time, the theoretical integrations of the partial derivatives obtained from the differentiation of the B-C-G law. The findings from this study were thoroughly compared with experimental data. It was verified that the integration methods proposed in this study provided the detailed analysis on the differential properties of ΔP, ΔV, and ΔT accurately. Furthermore, the stepwise analysis of the integration of the partial derivatives revealed that the state changes of gases inherently involve energy loss, which can be defined as the efficiency. In other words, this study demonstrated that the state changes of all matters include energy loss, and it is a natural phenomenon. Therefore, it can be said that this study suggests the theoretical method to select the most efficient process for the state change of a material.

Authors

Publication Details

Journal
Results in Engineering
Published
2024-12-29
DOI
https://doi.org/10.1016/j.rineng.2024.103769
Citations
2
Primary Topic
Phase Equilibria and Thermodynamics
Type
article
Field-Weighted Citation Impact
0.37
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article

Information hidden in the state change of a gas obtained from the theoretical integrations of the partial derivatives

Soon-Ho Choi, Se-Dong Kim
2 citations
Results in Engineering
Phase Equilibria and Thermodynamics
0.37
article

Information hidden in the state change of a gas obtained from the theoretical integrations of the partial derivatives

Soon-Ho Choi, Se-Dong Kim
article en
2 citations

Abstract

The calculations of the change in the gas state are critical in most engineering applications. Generally, engineers and scientists use Boyle-Charles-Gay Lussac's (B-C-G) law of P1V1/T1 = P2V2/T2 to calculate pressure (P), volume (V), and temperature (T) of gases and vapors. Although the B-C-G law provides accurate gas properties of P-V-T, it does not give any specific information about the process of a state change by which gases and vapors change their state. In this study, the authors performed, for the first time, the theoretical integrations of the partial derivatives obtained from the differentiation of the B-C-G law. The findings from this study were thoroughly compared with experimental data. It was verified that the integration methods proposed in this study provided the detailed analysis on the differential properties of ΔP, ΔV, and ΔT accurately. Furthermore, the stepwise analysis of the integration of the partial derivatives revealed that the state changes of gases inherently involve energy loss, which can be defined as the efficiency. In other words, this study demonstrated that the state changes of all matters include energy loss, and it is a natural phenomenon. Therefore, it can be said that this study suggests the theoretical method to select the most efficient process for the state change of a material.

Results in EngineeringVol. 25
Reduced inequalities
Openalex Percentile: Top 41%
Phase Equilibria and Thermodynamics
0.37
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Information hidden in the state change of a gas obtained from the theoretical integrations of the partial derivatives — Soon-Ho Choi, Se-Dong Kim · Results in Engineering (2024) | TGRS Research Map | TGRS