Two-dimensional squishy glass: yielding under oscillatory shear

The yielding response to an imposed oscillatory shear is investigated for a model two-dimensional dense glass composed of bidisperse, deformable polymer rings, with the ring stiffness being the control parameter. In the quiescent glassy state, the more flexible rings exhibit a broader spectrum of shape fluctuations, which becomes increasingly constrained with increasing ring stiffness. Under shear, the highly packed rings yield, <i>i.e.</i> the thermal assembly loses rigidity, with the threshold yield strain increasing significantly with decreasing ring stiffness. Further, the rings display significant deviations in their shape compared to their unsheared counterparts. This study provides insights into the interplay between shape changes and translational rearrangements under shear, thus contributing to the understanding of yielding transition in densely packed, deformable polymer systems.

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Publication Details

Journal
Soft Matter
Published
2024-12-28
DOI
https://doi.org/10.1039/d4sm01069h
Citations
1
Primary Topic
Advanced Optical Imaging Technologies
Type
article
Field-Weighted Citation Impact
0.32
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article

Two-dimensional squishy glass: yielding under oscillatory shear

Pinaki Chaudhuri, Rahul Nayak, Satyavani Vemparala, Sayantan Ghosh
1 citations
Soft Matter
Advanced Optical Imaging Technologies
0.32
article

Two-dimensional squishy glass: yielding under oscillatory shear

Pinaki Chaudhuri, Rahul Nayak, Satyavani Vemparala, Sayantan Ghosh
article en
1 citations

Abstract

The yielding response to an imposed oscillatory shear is investigated for a model two-dimensional dense glass composed of bidisperse, deformable polymer rings, with the ring stiffness being the control parameter. In the quiescent glassy state, the more flexible rings exhibit a broader spectrum of shape fluctuations, which becomes increasingly constrained with increasing ring stiffness. Under shear, the highly packed rings yield, <i>i.e.</i> the thermal assembly loses rigidity, with the threshold yield strain increasing significantly with decreasing ring stiffness. Further, the rings display significant deviations in their shape compared to their unsheared counterparts. This study provides insights into the interplay between shape changes and translational rearrangements under shear, thus contributing to the understanding of yielding transition in densely packed, deformable polymer systems.

Soft MatterVol. 21(7)
Homi Bhabha National Institute (IN), Institute of Mathematical Sciences (IN)
Openalex Percentile: Top 33%
Advanced Optical Imaging Technologies
0.32
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