Investigation of Solubility Behavior, Data Correlations and Thermodynamic Study of Succinic Acid in Water + Methanol Mixtures at Various Temperatures

By using a gravimetric approach, the solubility of succinic acid in water, methanol, and water + methanol binary solvent was determined at temperatures between 305.15 and 313.15 K in the local atmosphere. The findings of the experiment demonstrated a positive correlation between temperature rise and succinic acid solubility. In order to better correlate and match the experimental results, the thermodynamic models van't Hoff and Apelblat were used. Additionally, the DFT investigation was conducted to look into how solvent-solute interactions affected solubility. In addition, the dissolving process's thermodynamic characteristics were computed, and the findings suggested that it was an entropy-driven, spontaneous, endothermic process.

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Publication Details

Journal
Material Science Research India
Published
2024-12-10
DOI
https://doi.org/10.13005/msri/210304
Primary Topic
Crystallization and Solubility Studies
Type
article
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article

Investigation of Solubility Behavior, Data Correlations and Thermodynamic Study of Succinic Acid in Water + Methanol Mixtures at Various Temperatures

Sandip B. Nahire
1 links
Material Science Research India
Crystallization and Solubility Studies
article

Investigation of Solubility Behavior, Data Correlations and Thermodynamic Study of Succinic Acid in Water + Methanol Mixtures at Various Temperatures

Sandip B. Nahire
article en

Abstract

By using a gravimetric approach, the solubility of succinic acid in water, methanol, and water + methanol binary solvent was determined at temperatures between 305.15 and 313.15 K in the local atmosphere. The findings of the experiment demonstrated a positive correlation between temperature rise and succinic acid solubility. In order to better correlate and match the experimental results, the thermodynamic models van't Hoff and Apelblat were used. Additionally, the DFT investigation was conducted to look into how solvent-solute interactions affected solubility. In addition, the dissolving process's thermodynamic characteristics were computed, and the findings suggested that it was an entropy-driven, spontaneous, endothermic process.

Material Science Research IndiaVol. 21(3)
Openalex Percentile: Top 84%
Crystallization and Solubility Studies
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