Reducing noble metal dependence: oxygen evolution reaction with a Ru-minimized Bi<sub>2</sub>Ru<sub>2</sub>O<sub>7</sub>@MOF-801 composite
Developing efficient and noble metal-minimized electrocatalysts for the oxygen evolution reactions (OER) is critical for energy conversion reactions. Here we present Ru-minimized Bi<sub>2</sub>Ru<sub>2</sub>O<sub>7</sub>@MOF-801 that synergistically combines the high catalytic activity of the bimetallic oxide with the unique structural and hydrophilic properties of the Zr-MOF. The composite achieves superior OER performance with a low overpotential of 307 mV at 50 mA cm<sup>-2</sup> and a Tafel slope of 99.8 mV dec<sup>-1</sup> surpassing those of pure Bi<sub>2</sub>Ru<sub>2</sub>O<sub>7</sub> and MOF-801. Comparative testing with cutting-edge catalysts shows that using less Ru and incorporating a MOF work well together, providing a promising way to make high-performance OER catalysts that are also cost-effective by integrating the MOF for energy applications.
Authors
- S. Vadivel (ORCID: https://orcid.org/0000-0003-0318-192X)
- K. C. Gupta (ORCID: https://orcid.org/0000-0001-7226-3561)
- P. Sujita
- Varun Gopal
- S. Sarmila
Institutions
- SRM Institute of Science and Technology (IN)
Publication Details
- Journal
- Nanoscale
- Published
- 2024-12-27
- DOI
- https://doi.org/10.1039/d4nr04140b
- Citations
- 3
- Primary Topic
- Electrocatalysts for Energy Conversion
- Type
- article
- Field-Weighted Citation Impact
- 0.31
Funders
- SRM Institute of Science and Technology
- Science and Engineering Research Board