Ex Situ pH‐Induced Reversible Wettability Switching for an Environmentally Robust and High‐Efficiency Stain‐Proof Coating

Developing superwetting coatings with environmental adaptability is critical for sustainable industrial applications. However, traditional anti-wetting coatings often fall short due to their susceptibility to environmental factors (UV light, temperature, mold growth, and abrasion) and inadequate stain resistance in complex media. Herein, a durable ex situ pH-responsive coating with reversible wettability switching, engineered by integrating hydrophobic polydimethylsiloxane and tertiary amine structures is presented. The resulting hierarchical micro-nano surface structure, combined with a trapped air cushion, ensures low water adhesion and stable superhydrophobicity. Notably, after ex situ pH treatment, the modulation of surface N⁺ content synergistically interacts with polydimethylsiloxane chains, enabling a controlled transition in surface wettability from 150° to 68.5°, which can spontaneously revert to a hydrophobic state upon heating and drying. This transition enhances stain resistance in both air and underwater environments, resulting in a 17.2% increase in detergency compared to superhydrophobic controls. Moreover, the coating demonstrates remarkable durability, with no staining, peeling, or mildew growth (grade 0) even after 1500 h of UV radiation and 28 days of mildew resistance testing. This work offers a highly adaptable and stain-resistant coating for applications in building and infrastructure protection, as well as in smart textiles designed for multi-media decontamination.