Electrochemical Conversion of <i>N</i>‐Sulfinylamines to Sulfonimidoyl Fluorides

Comprehensive Summary The invention of novel linkers is a long‐lasting task in the area of the sulfur(VI) fluoride exchange reaction (SuFEx). Compared with the most frequently investigated sulfonyl fluorides, synthetic accessibility toward its mono‐aza isostere, i.e. , sulfonimidoyl fluorides is still limited. Herein, we report an electrochemical carbonfluorination of the readily available N ‐sulfinylamines to access various aryl and alkyl sulfonimidoyl fluorides. The transformation is characterized by the ready availability of starting materials, mild reaction conditions, and obviating metal catalysts and chemical oxidants.