Modulation of polypropylene dielectric properties using graphene defect engineering

Abstract Regulating the dielectric properties of base stations is crucial for advancing 5G technology. This study presents the preparation of a series of graphene/polypropylene (PP) composites by blending various types and concentrations of graphene with PP using a melt blending process. The effect of different graphene types (graphene oxide, multilayer graphene, and exfoliated graphene) and concentrations (0.1, 0.5, 1, and 2 wt%) on the composites was characterized using scanning electron microscope (SEM), X‐ray diffraction (XRD), differential scanning calorimeter (DSC), impedance analyzer, rotational rheometer, and thermal gravimetric analyzer (TGA). Results show that high shear force and temperature during preparation ensure the mechanical and thermal properties of the composites. Specifically, the permittivity decreased by up to 18% with the incorporation of 1% multilayer graphene (MGE). The optimal performance was achieved with MGE compared to graphene oxide (GO) and exfoliated graphene (GE), as the composites exhibited enhanced mechanical strength, thermal stability, and lower permittivitys. This work suggests significant application prospects for PP composite materials in the 5G field due to the excellent characteristics of graphene. Highlights Graphene significantly reduces the permittivity of polypropylene. Strong interfacial bonding exists between moderate amounts of graphene and PP. Graphene boosts substrate crystallization to reduce permittivity. Composite permittivity rises with filler's permittivity increase.