Kinetics, quantum yield and mechanism of the decatungstate-catalyzed photooxidation of C–H hydrogen donors: role of the persistent radical effect
We report absolute rate constants for the reaction of triplet decatungstate ( 3 DT*) with hydroperoxides using laser techniques and taking advantage of its recently discovered NIR phosphorescence.
Authors
- J. C. Scaiano (ORCID: https://orcid.org/0000-0002-4838-7123)
- Saba Didarataee (ORCID: https://orcid.org/0009-0009-6789-9958)
- Julia Ong
- Neeraj Joshi (ORCID: https://orcid.org/0000-0002-8735-3874)
- Anastasiia Suprun
Institutions
- University of Ottawa (CA)
Publication Details
- Journal
- Catalysis Science & Technology
- Published
- 2024-12-26
- DOI
- https://doi.org/10.1039/d4cy01358a
- Citations
- 5
- Primary Topic
- Radical Photochemical Reactions
- Type
- article
- Field-Weighted Citation Impact
- 1.25