Visible-Light-Induced Synthesis of Azlactone Monomers and Dimers utilizing SF<sub>6</sub> as both Condensation Agent and Oxidant
The visible-light-mediated continuous dehydration condensation and oxidative radical dimerization, featuring sulfur hexafluoride (SF<sub>6</sub>) as both a condensation agent and oxidant, have been developed. This photocatalytic method uses commercially available N-protected amino acids as substrates and enables the formation of azlactone monomers and dimers, facilitating efficient utilization and degradation of greenhouse gas SF<sub>6</sub>.
Authors
- Shan Zhu (ORCID: https://orcid.org/0000-0002-4473-6242)
- Xi‐Sheng Wang (ORCID: https://orcid.org/0000-0003-2398-5669)
- Yan He (ORCID: https://orcid.org/0000-0003-2679-2547)
- Ruo‐Xing Jin (ORCID: https://orcid.org/0000-0002-6381-148X)
- Yong Yang (ORCID: https://orcid.org/0000-0001-7304-7529)
- Zhiyuan Liu (ORCID: https://orcid.org/0000-0002-6331-0810)
Institutions
- University of Science and Technology of China (CN)
- Electric Power Research Institute (US)
- Institution of Engineering and Technology (GB)
Publication Details
- Journal
- Organic Letters
- Published
- 2024-12-25
- DOI
- https://doi.org/10.1021/acs.orglett.4c03700
- Primary Topic
- Radical Photochemical Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Science and Technology Foundation of State Grid Corporation of China