Synthesis, Crystal Structure and Magnetic Properties of Y<sub>3–x</sub>Cex(Fe<sub>0.5</sub>Ga<sub>0.5</sub>)<sub>5</sub>O<sub>12</sub> (<i>х</i> = 0, 0.5)

The specific magnetisation and magnetic susceptibility of ferrogranates of the composition Y3–xCex(Fe0.5Ga0.5)5O12 (x = 0, 0.5) obtained by the gel combustion method have been measured. It was found that after synthesis and subsequent crystallisation at pressure ≈ 10–2 Pa at 1023 K for 2 h, the temperature of magnetic phase transformation in the studied compositions Y3–xCex(Fe0.5Ga0.5)5O12 increases with the replacement of yttrium ions Y3+ by Ce3+. Partial substitution of iron ions in the ferrogranate lattice by gallium leads to the appearance of antiferromagnetic ordering with sufficiently high Curie-Weiss temperature Θef.

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Journal
Журнал неорганической химии
Published
2024-08-15
DOI
https://doi.org/10.31857/s0044457x24080022
Primary Topic
Advanced Condensed Matter Physics
Type
article
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article

Synthesis, Crystal Structure and Magnetic Properties of Y3–xCex(Fe0.5Ga0.5)5O12 (х = 0, 0.5)

Г. Е. Никифорова, M.N. Smirnova, K. I. Yanushkevich, Е. S. Romanova et al.
Журнал неорганической химии
Advanced Condensed Matter Physics
article

Synthesis, Crystal Structure and Magnetic Properties of Y3–xCex(Fe0.5Ga0.5)5O12 (х = 0, 0.5)

Г. Е. Никифорова, M.N. Smirnova, K. I. Yanushkevich, Е. S. Romanova, В. А. Кецко
article en

Abstract

The specific magnetisation and magnetic susceptibility of ferrogranates of the composition Y3–xCex(Fe0.5Ga0.5)5O12 (x = 0, 0.5) obtained by the gel combustion method have been measured. It was found that after synthesis and subsequent crystallisation at pressure ≈ 10–2 Pa at 1023 K for 2 h, the temperature of magnetic phase transformation in the studied compositions Y3–xCex(Fe0.5Ga0.5)5O12 increases with the replacement of yttrium ions Y3+ by Ce3+. Partial substitution of iron ions in the ferrogranate lattice by gallium leads to the appearance of antiferromagnetic ordering with sufficiently high Curie-Weiss temperature Θef.

Журнал неорганической химииVol. 69(8)
National Academy of Sciences of Belarus (BY), NS Kurnakova Institute of General and Inorganic Chemistry (RU)
Openalex Percentile: Top 85%
Advanced Condensed Matter Physics
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