Synthesis, Crystal Structure and Magnetic Properties of Y<sub>3–x</sub>Cex(Fe<sub>0.5</sub>Ga<sub>0.5</sub>)<sub>5</sub>O<sub>12</sub> (<i>х</i> = 0, 0.5)
The specific magnetisation and magnetic susceptibility of ferrogranates of the composition Y3–xCex(Fe0.5Ga0.5)5O12 (x = 0, 0.5) obtained by the gel combustion method have been measured. It was found that after synthesis and subsequent crystallisation at pressure ≈ 10–2 Pa at 1023 K for 2 h, the temperature of magnetic phase transformation in the studied compositions Y3–xCex(Fe0.5Ga0.5)5O12 increases with the replacement of yttrium ions Y3+ by Ce3+. Partial substitution of iron ions in the ferrogranate lattice by gallium leads to the appearance of antiferromagnetic ordering with sufficiently high Curie-Weiss temperature Θef.
Authors
- Г. Е. Никифорова (ORCID: https://orcid.org/0000-0002-2892-6054)
- M.N. Smirnova (ORCID: https://orcid.org/0000-0002-0731-3240)
- K. I. Yanushkevich (ORCID: https://orcid.org/0000-0003-3763-6582)
- Е. S. Romanova
- В. А. Кецко (ORCID: https://orcid.org/0000-0002-2075-1755)
Institutions
- National Academy of Sciences of Belarus (BY)
- NS Kurnakova Institute of General and Inorganic Chemistry (RU)
Publication Details
- Journal
- Журнал неорганической химии
- Published
- 2024-08-15
- DOI
- https://doi.org/10.31857/s0044457x24080022
- Primary Topic
- Advanced Condensed Matter Physics
- Type
- article
- Field-Weighted Citation Impact
- 0.00