Di- and Octanuclear Iodoantimonates(III) with 1,2-Dimethylpyridinium and 3-Bromo-1-Ethyllpyridinium: Crystal Structure and Physico-Chemical Properties
By the reaction of SbI3 and iodides of the corresponding cations in organic solvents, two new antimony complexes were obtained — (3-Br-1-EtPy)3[Sb2I9] (1), (1,2-MePy)4[Sb8I28] (2). The features of the crystal structure of the compounds were determined by X-ray diffraction. The complexes are thermally stable up to at least 200°C and have a band gap of about 2.2 eV.
Authors
- Maksim Sokolov (ORCID: https://orcid.org/0000-0001-5244-6301)
- Sergey A. Adonin (ORCID: https://orcid.org/0000-0002-9889-5273)
- Irina A. Shentseva
- Vladimir R. Shayapov (ORCID: https://orcid.org/0000-0001-7647-7743)
- Andrey N. Usoltsev (ORCID: https://orcid.org/0000-0003-3980-5028)
- Nikita A. Korobeynikov (ORCID: https://orcid.org/0000-0003-3399-5975)
- K. A. Tagiltsev
Institutions
- Novosibirsk State University (RU)
- A.E. Favorsky Irkutsk Institute of Chemistry (RU)
- Nikolaev Institute of Inorganic Chemistry (RU)
Publication Details
- Journal
- Журнал неорганической химии
- Published
- 2024-08-15
- DOI
- https://doi.org/10.31857/s0044457x24080053
- Primary Topic
- Crystal structures of chemical compounds
- Type
- article
- Field-Weighted Citation Impact
- 0.00