Synthesis and luminescence of 3-(pyridine-2-yl)-1,2,4-triazine-based Ir(III) complexes

A series of novel iridium(III) complexes containing 5-N-(aryl)-amino- or 5-cycloamino-3-(pyridine-2-yl)-1,2,4-triazine ligands was obtained. These complexes exhibited red luminescence in solution as well as in the solid state. Based on the DFT studies it was suggested that N(2) atom of the 1,2,4-triazine core is preferable to N(4) one as the coordination site in the complexes of Ir(III).

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Publication Details

Journal
Chimica Techno Acta
Published
2024-12-18
DOI
https://doi.org/10.15826/chimtech.2025.12.1.09
Primary Topic
Organic Light-Emitting Diodes Research
Type
article
Field-Weighted Citation Impact
0.00

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article

Synthesis and luminescence of 3-(pyridine-2-yl)-1,2,4-triazine-based Ir(III) complexes

Alexey P. Krinochkin, Dmitry S. Kopchuk, Igor S. Коvalev, Мaria I. Valieva et al.
Chimica Techno Acta
Organic Light-Emitting Diodes Research
article

Synthesis and luminescence of 3-(pyridine-2-yl)-1,2,4-triazine-based Ir(III) complexes

Alexey P. Krinochkin, Dmitry S. Kopchuk, Igor S. Коvalev, Мaria I. Valieva, Olga V. Shabunina, Ya. K. Shtaitz, Albert F. Khasanov, B. S. M. Al-Ghezi, Nikita S. Glebov, Grigory V. Zyryanov, Maria V. Sangalova, Alena A. Noskova
article en

Abstract

A series of novel iridium(III) complexes containing 5-N-(aryl)-amino- or 5-cycloamino-3-(pyridine-2-yl)-1,2,4-triazine ligands was obtained. These complexes exhibited red luminescence in solution as well as in the solid state. Based on the DFT studies it was suggested that N(2) atom of the 1,2,4-triazine core is preferable to N(4) one as the coordination site in the complexes of Ir(III).

Chimica Techno ActaVol. 12(1)
Ural Federal University (RU), Sirius University of Science and Technology (RU), Institute of Organic Synthesis (RU)
Russian Science Foundation
Openalex Percentile: Top 78%
Organic Light-Emitting Diodes Research
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Synthesis and luminescence of 3-(pyridine-2-yl)-1,2,4-triazine-based Ir(III) complexes — Alexey P. Krinochkin, Dmitry S. Kopchuk, et al. · Chimica Techno Acta (2024) | TGRS Research Map | TGRS