Au-Acyclic Diaminocarbene-Linked Homochiral Covalent Organic Frameworks: Synthesis and Asymmetric Catalytic Application
Chiral covalent organic framework (CCOF)-based heterogeneous catalysts are the new hot topic in asymmetric catalysis. The chiral metal-acyclic diaminocarbene complexes (M-ADCs), on the other hand, make up a powerful class of homogeneous catalysts for various asymmetric organic transformations. The integration of chiral M-ADCs with COFs into a single platform will undoubtedly lead to a new breed of heterogeneous asymmetric catalysts. Here, we report the synthesis of Au-ADC-linked CCOFs via a metal-mediated nucleophilic addition approach. This research not only provides a new type of COF linkage but also affords a new kind of heterogeneous catalysts for asymmetric catalysis.
Authors
- Congcong Yin (ORCID: https://orcid.org/0000-0002-1533-8018)
- Jian‐Ping Ma (ORCID: https://orcid.org/0000-0002-5300-3307)
- Yu‐Bin Dong (ORCID: https://orcid.org/0000-0002-9698-8863)
- Jing‐Lan Kan (ORCID: https://orcid.org/0000-0003-2874-9139)
- Jian‐Biao Liu (ORCID: https://orcid.org/0000-0002-2550-3355)
- Ying Dong (ORCID: https://orcid.org/0000-0002-4397-4695)
- C. Chang
Institutions
- Shandong Normal University (CN)
- Ministry of Education (ME)
Publication Details
- Journal
- Chemistry of Materials
- Published
- 2024-12-24
- DOI
- https://doi.org/10.1021/acs.chemmater.4c02884
- Citations
- 6
- Primary Topic
- Covalent Organic Framework Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.70
Funders
- National Natural Science Foundation of China
- Natural Science Foundation of Shandong Province
- Taishan Scholar Project of Shandong Province
- Project of Shandong Province Higher Educational Science and Technology Program