<i>trans</i>-Bis(quinoline-8-amine-κ<sup>2</sup> <i>N</i>,<i>N</i>′)bis(1,1,3,3-tetracyano-2-methoxypropenido-κ<i>N</i>)iron(II)

The title compound, [Fe(C<sub>8</sub>H<sub>3</sub>N<sub>4</sub>O)<sub>2</sub>(C<sub>9</sub>H<sub>8</sub>N<sub>2</sub>)<sub>2</sub>], was synthesized solvothermally. The complex exhibits a distorted octa-hedral coordination geometry. The Fe<sup>2+</sup> ion is located on an inversion centre. The octa-hedral FeN<sub>6</sub> coordination sphere is composed of bidentate quinoline-8-amine in the equatorial sites while the axial sites are occupied by 1,1,3,3-tetra-cyano-2-meth-oxy-propenide anions. The crystal structure features hydrogen bonds parallel to the crystallographic <i>b</i> axis and parallel to (110).

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IUCrData
Published
2024-12-20
DOI
https://doi.org/10.1107/s2414314624012197
Primary Topic
Metal complexes synthesis and properties
Type
article
Field-Weighted Citation Impact
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article

trans-Bis(quinoline-8-amine-κ2 N,N′)bis(1,1,3,3-tetracyano-2-methoxypropenido-κN)iron(II)

Mohammed Hadi Al–Douh, Zouaoui Setifi, Uwe Böhme, Fatima Setifi et al.
IUCrData
Metal complexes synthesis and properties
article

trans-Bis(quinoline-8-amine-κ2 N,N′)bis(1,1,3,3-tetracyano-2-methoxypropenido-κN)iron(II)

Mohammed Hadi Al–Douh, Zouaoui Setifi, Uwe Böhme, Fatima Setifi, Achouak Satour
article en

Abstract

The title compound, [Fe(C<sub>8</sub>H<sub>3</sub>N<sub>4</sub>O)<sub>2</sub>(C<sub>9</sub>H<sub>8</sub>N<sub>2</sub>)<sub>2</sub>], was synthesized solvothermally. The complex exhibits a distorted octa-hedral coordination geometry. The Fe<sup>2+</sup> ion is located on an inversion centre. The octa-hedral FeN<sub>6</sub> coordination sphere is composed of bidentate quinoline-8-amine in the equatorial sites while the axial sites are occupied by 1,1,3,3-tetra-cyano-2-meth-oxy-propenide anions. The crystal structure features hydrogen bonds parallel to the crystallographic <i>b</i> axis and parallel to (110).

IUCrDataVol. 9(12)
Hadhramout University (YE), University Ferhat Abbas of Setif (DZ), TU Bergakademie Freiberg (DE), University of Skikda (DZ)
Région Normandie, Direction Générale de la Recherche Scientifique et du Développement Technologique
Openalex Percentile: Top 59%
Metal complexes synthesis and properties
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