Evaluation of the Wear of Ni 200 Alloy After Long-Term Carbon Capture in Molten Salts Process

Reducing CO₂ emissions is one of the major challenges facing the modern world. The overall goal is to limit global warming and prevent catastrophic climate change. One of the many methods for reducing carbon dioxide emissions involves capturing, utilizing, and storing it at the source. The Carbon Capture in Molten Salts (CCMS) technique is considered potentially attractive and promising, although it has so far only been tested at the laboratory scale. This study evaluates the wear of the main structural components of a prototype for CO₂ capture in molten salts-a device designed and tested in the laboratories of AGH University of Kraków. The evaluation focused on a gas barbotage lance and a reactor chamber (made from Nickel 200 Alloy), which were in continuous, long-term (800 h) contact with molten salts CaCl₂-CaF₂-CaO-CaCO₃ at temperatures of 700-940 °C in an atmosphere of N₂-CO₂. The research used light microscopy, SEM, X-ray, computed tomography (CT), and 3D scanning. The results indicate the greatest wear on the part of the lance submerged in the molten salts (3.9 mm/year). The most likely wear mechanism involves grain growth and intergranular corrosion. Nickel reactions with the aggressive salt environment and its components cannot be ruled out. Additionally, the applied research methods enabled the identification of material discontinuities in the reactor chamber (mainly in welded areas), pitting on its surface, and uneven wear in different zones.