C–H silylation and boronation enabled by alkyne insertion/vinyl to aryl 1,5-palladium migration
An alkyne insertion/vinyl to aryl 1,5-palladium migration strategy has been disclosed for the α-C–H silylation and boronation of a naphthalene ring, enabling the synthesis of silylated and boronated benzo[ f ]isoquinolines and benzo[ f ]isochromenes.
Authors
- Yun Teh S. Liang (ORCID: https://orcid.org/0000-0002-2550-9220)
- Zhengrui Zhou
- Yuan Yang (ORCID: https://orcid.org/0000-0002-9061-1758)
- Zhendong Cheng
- Liwei Zhou (ORCID: https://orcid.org/0000-0001-5666-8315)
- Weiwei Xu
- Xuliang Tan
Institutions
- Changsha Medical University (CN)
- Hunan Normal University (CN)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2024-12-23
- DOI
- https://doi.org/10.1039/d4qo02224f
- Citations
- 6
- Primary Topic
- Catalytic Cross-Coupling Reactions
- Type
- article
- Field-Weighted Citation Impact
- 1.50