Fluorinated organosilane polycondensation enables a robust Si anode for lithium storage

The chemistry of fluorinated organosilane polycondensation is utilized to form a robust Si anode with F-doped SiO<sub><i>x</i></sub>/C composite coating. F-doping promotes the formation of not only a coating rich in less electrochemically active Si<sup>4+</sup> species but also an LiF-rich solid-state electrolyte interphase, enabling an Si anode with a long life of 500 cycles at large current densities for lithium storage.

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Publication Details

Journal
Chemical Communications
Published
2024-12-23
DOI
https://doi.org/10.1039/d4cc06142j
Citations
2
Primary Topic
Advancements in Battery Materials
Type
article
Field-Weighted Citation Impact
0.42

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article

Fluorinated organosilane polycondensation enables a robust Si anode for lithium storage

Li ZhengYue, Jianping Huang, Zhiyu Wang
2 citations
Chemical Communications
Advancements in Battery Materials
0.42
article

Fluorinated organosilane polycondensation enables a robust Si anode for lithium storage

Li ZhengYue, Jianping Huang, Zhiyu Wang
article en
2 citations

Abstract

The chemistry of fluorinated organosilane polycondensation is utilized to form a robust Si anode with F-doped SiO<sub><i>x</i></sub>/C composite coating. F-doping promotes the formation of not only a coating rich in less electrochemically active Si<sup>4+</sup> species but also an LiF-rich solid-state electrolyte interphase, enabling an Si anode with a long life of 500 cycles at large current densities for lithium storage.

Chemical CommunicationsVol. 61(8)
Dalian University of Technology (CN), Dalian University (CN)
National Natural Science Foundation of China, National Key Research and Development Program of China, Fundamental Research Funds for the Central Universities
Clean water and sanitation
Openalex Percentile: Top 36%
Advancements in Battery Materials
0.42
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