Photoinduced Autopromoted Ni-Catalyzed Three-Component Arylsulfonation Inspired by Density Functional Theory/Time-Dependent Density Functional Theory-Simulated Photoactive Nickel Species
The structure of the novel photoactive nickel species was simulated by density functional theory (DFT)/time-dependent density functional theory (TD-DFT) calculations. The application of the simplified photoactive nickel catalyst was demonstrated in a photoinduced nickel-catalyzed three-component arylsulfonation of 1,6-enynes. This reaction was autopromoted and proceeded in the absence of an additional photocatalyst. This methodology exhibited mild conditions, a broad substrate scope, and high efficiency.
Authors
- Xiaolin Liang (ORCID: https://orcid.org/0000-0002-5479-4067)
- Peng Wu (ORCID: https://orcid.org/0000-0002-0186-1086)
- Duo‐Duo Hu (ORCID: https://orcid.org/0009-0008-3104-6120)
- Qian Gao
- Feng Zhang (ORCID: https://orcid.org/0000-0003-1949-8964)
- Hongliang Wang (ORCID: https://orcid.org/0000-0001-9629-1743)
- Yan Li (ORCID: https://orcid.org/0000-0002-2708-123X)
- Xiu‐Fen Cheng
Institutions
- University of Science and Technology of China (CN)
- Max Planck Institute of Molecular Physiology (DE)
- Shandong First Medical University (CN)
- Chemical Genomics Centre (DE)
Publication Details
- Journal
- Organic Letters
- Published
- 2024-12-23
- DOI
- https://doi.org/10.1021/acs.orglett.4c04222
- Citations
- 2
- Primary Topic
- Sulfur-Based Synthesis Techniques
- Type
- article
- Field-Weighted Citation Impact
- 0.50
Funders
- National Natural Science Foundation of China
- Ministry of Education of the People's Republic of China
- Max-Planck-Gesellschaft
- Natural Science Foundation of Shandong Province
- Taishan Scholar Project of Shandong Province
- Shandong First Medical University