NHC–Au–xanthate complexes
We report the synthesis, isolation, and comprehensive characterization of N-heterocyclic carbene gold xanthate (NHC-Au-X, X - xanthate) complexes. These easily accessible complexes demonstrate significant versatility as photocatalysts, facilitating [2+2]-cycloadditions, and as π-catalysts in the intramolecular hydroxylation of allenes and hydrohydrazination of alkynes.
Authors
- Oksana Danylyuk (ORCID: https://orcid.org/0000-0002-3653-2418)
- Michał Michalak (ORCID: https://orcid.org/0000-0002-1193-1551)
- Aleksander Gorski (ORCID: https://orcid.org/0000-0002-5182-5614)
- Halina Car (ORCID: https://orcid.org/0000-0002-4926-3405)
- Supratim Chakraborty
- Katarzyna Niemirowicz-Laskowska
Institutions
- Medical University of Białystok (PL)
- Institute of Organic Chemistry (PL)
- Institute of Physical Chemistry (PL)
- Polish Academy of Sciences (PL)
Publication Details
- Journal
- Chemical Communications
- Published
- 2024-12-23
- DOI
- https://doi.org/10.1039/d4cc05193a
- Primary Topic
- N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00