Ca<sup>2+</sup> Electrochemical Intercalation in Fe[Fe(CN)<sub>6</sub>]<sub>1–<i>y</i></sub> Berlin Green
Fe[Fe(CN)6]0.83·2.1 H2O has been prepared by precipitation and exhibits a cubic crystal structure (Fm3̅m, a = 10.1896(8) Å). Reversible redox activity in cells containing either sodium or calcium based electrolytes (capacity around 100 mAh/g) induces structural changes that have been followed by operando synchrotron X-ray diffraction.
Authors
- M. Rosa Palacín (ORCID: https://orcid.org/0000-0001-7351-2005)
- Ashley P. Black (ORCID: https://orcid.org/0000-0001-7929-5144)
- Carlos Frontera (ORCID: https://orcid.org/0000-0002-0091-4756)
- Alejandro Ramo-Irurre (ORCID: https://orcid.org/0009-0006-8743-4531)
Institutions
- Institut de Ciència de Materials de Barcelona (ES)
Publication Details
- Journal
- ACS Applied Energy Materials
- Published
- 2024-12-23
- DOI
- https://doi.org/10.1021/acsaem.4c02623
- Citations
- 3
- Primary Topic
- Advancements in Battery Materials
- Type
- article
- Field-Weighted Citation Impact
- 0.63
Funders
- Agencia Estatal de Investigación