Enhancing Water Management with Three-Dimensionally Micropatterned Anion Exchange Membranes for Alkaline Fuel Cells
Alkaline exchange membrane fuel cells (AEMFCs) offer a promising solution for clean hydrogen utilization. However, effective water management remains a challenge due to the concurrent generation and consumption of water at the electrodes, which impacts the efficiency of AEMFCs at high current densities. Here, we report the fabrication of alkaline fuel cells with improved water management by employing a three-dimensionally patterned alkaline exchange membrane (AEM) at the interface with the cathode catalyst layer. This micropatterned AEM, made by soft lithography, enables a power density of 628 mW cm–2 at a current density of 1100 mA cm–2, representing an approximately 50% performance improvement over identical AEMFCs made from conventional two-dimensional AEMs. The patterned AEM also improves platinum utilization due to the increased catalyst-membrane contact area and tailored catalyst layer thickness.
Authors
- Tianyue Gao (ORCID: https://orcid.org/0000-0002-1293-8552)
- Leanna Schulte (ORCID: https://orcid.org/0000-0002-6970-8811)
- Thomas E. Mallouk (ORCID: https://orcid.org/0000-0003-4599-4208)
- Chulsung Bae (ORCID: https://orcid.org/0000-0002-9026-3319)
- Chang Liu (ORCID: https://orcid.org/0000-0002-7568-0608)
- Heemin Park (ORCID: https://orcid.org/0000-0001-5164-1551)
- Sariah Marth
Institutions
- Oak Ridge National Laboratory (US)
- Rensselaer Polytechnic Institute (US)
- University of Pennsylvania (US)
Publication Details
- Journal
- ACS Energy Letters
- Published
- 2024-12-23
- DOI
- https://doi.org/10.1021/acsenergylett.4c02824
- Citations
- 3
- Primary Topic
- Fuel Cells and Related Materials
- Type
- article
- Field-Weighted Citation Impact
- 0.63
Funders
- National Science Foundation
- Vagelos Institute for Energy Science and Technology, University of Pennsylvania
- Energy Frontier Research Centers