Features of the Isotopic Distribution of Uranium at the Interface between Polar and Nonpolar Media

The adsorption of UO2(NO3)2·2TBP complexes in a heterogeneous system at the interface of a polar 5.6 М HNO3 solution and a nonpolar polypropylene (C3H6)n surface was studied. The isotopic distribution of uranium changes at the vertical interface of the media. The kinetics of the extraction of UO2(NO3)2·2TBP complexes in the heterogeneous system is described by the Erofeev–Kolmogorov pseudo-first-order model and the Ho–McKay pseudo-second-order model.

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Publication Details

Journal
Bulletin of the Russian Academy of Sciences Physics
Published
2024-11-01
DOI
https://doi.org/10.1134/s1062873824708298
Primary Topic
Radioactive element chemistry and processing
Type
article
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article

Features of the Isotopic Distribution of Uranium at the Interface between Polar and Nonpolar Media

Ю. А. Митропольский, D. A. Rumyantseva, V. G. Zinoviev
Bulletin of the Russian Academy of Sciences Physics
Radioactive element chemistry and processing
article

Features of the Isotopic Distribution of Uranium at the Interface between Polar and Nonpolar Media

Ю. А. Митропольский, D. A. Rumyantseva, V. G. Zinoviev
article en

Abstract

The adsorption of UO2(NO3)2·2TBP complexes in a heterogeneous system at the interface of a polar 5.6 М HNO3 solution and a nonpolar polypropylene (C3H6)n surface was studied. The isotopic distribution of uranium changes at the vertical interface of the media. The kinetics of the extraction of UO2(NO3)2·2TBP complexes in the heterogeneous system is described by the Erofeev–Kolmogorov pseudo-first-order model and the Ho–McKay pseudo-second-order model.

Bulletin of the Russian Academy of Sciences PhysicsVol. 88(11)
Petersburg Nuclear Physics Institute (RU)
Openalex Percentile: Top 81%
Radioactive element chemistry and processing
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